Lateglacial to early Holocene multiproxy record from Loch Assynt,NW Scotland     

Ian Boomer  Ulrich von Grafenstein  Andy Moss 《Proceedings of the Geologists' Association. Geologists' Association》2012,123(1):109-116

A core, recovered from a water depth of 53 m in Loch Assynt, North-West Scotland, has yielded a 9 m sequence comprising two distinct units, an upper, organic-rich unit (Unit I, ca. 6 m) overlying a sequence of laminated clays, silts and sands (Unit II, ca. 3 m). The upper unit is essentially Holocene in age based upon three bulk AMS radiocarbon dates while a fourth radiocarbon date from Unit II confirms a late-glacial age for that interval and supports a broadly linear age–depth relationship. Distinct variations in the magnetic susceptibility record of the lower unit can be visually correlated to major changes in the Greenland ice core (GISP2), this together with pollen evidence supports the radiocarbon dating suggesting an age of approximately 11,000 to around 17,000 cal. BP for Unit II, with evidence for the Younger Dryas (Loch Lomond) stadial and the Bolling–Allerød climatic phases. Variations in the magnetic susceptibility record of the late-glacial sediments are thought to relate to climatically driven changes in soil cover and erosion rates. The multiproxy record from Loch Assynt indicates relatively continuous, sub-aqueous sedimentation during the last ～17,000 years, providing an approximate age for the initiation of modern Loch Assynt and supporting recent dates of moraine retreat lines in the Loanan Valley from about 14–15 ka BP. Pollen and chironomid sampling provides further insights to the history of this relatively deep water body and compliment existing high-resolution palaeo-precipitation records for the mid to late Holocene interval from speleothem archives within the loch catchment.  相似文献   

Concept for an integral approach to explore the behavior of rock salt caverns under thermo-mechanical cyclic loading in energy storage systems     

Elham Mahmoudi  Kavan Khaledi  Achim von Blumenthal  Diethard König  Tom Schanz 《Environmental Earth Sciences》2016,75(14):1069

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Effects of using inclined parametric echosounding on sub-bottom acoustic imaging and advances in buried object detection   总被引：1，自引：0，他引：1  

Jens Schneider von Deimling  Philipp Held  Peter Feldens  Dennis Wilken 《Geo-Marine Letters》2016,36(2):113-119

This study reports an adaptation of a parametric echosounder system using 15 kHz as secondary frequency to investigate the angular response of sub-bottom backscatter strength of layered mud, providing a new method for enhanced acoustic detection of buried targets. Adaptions to achieve both vertical (0°) and non-vertical inclination (1–15°, 30°, 45° and 60°) comprise mechanical tilting of the acoustic transducer and electronic beam steering. Data were acquired at 18 m water depth at a study site characterized by a flat, muddy seafloor where a 0.1 m diameter power cable lies 1–2 m below the seafloor. Surveying the cable with vertical incidence revealed that the buried cable can hardly be discriminated against the backscatter strength of the layered mud. However, the backscatter strength of layered mud decreases strongly at >3±0.5° incidence and the layered mud echo pattern vanishes beyond 5°. As a consequence, the backscatter pattern of the buried cable is very pronounced in acoustic images gathered at 15°, 30°, 45° and 60° incidence. The size of the cable echo pattern increases linearly with incidence. These effects are attributed to reflection loss from layered mud at larger incidence and to the scattering of the 0.1 m diameter buried cable. Data analyses support the visual impression of superior detection of the cable with an up to 2.6-fold increase of the signal-to-noise ratio at 40° incidence compared to the vertical incidence case.  相似文献   

Towards a Higher Comparability of Geothermometric Data obtained by Raman Spectroscopy of Carbonaceous Material. Part I: Evaluation of Biasing Factors   总被引：1，自引：0，他引：1  

Nils K. Lünsdorf  Istvan Dunkl  Burkhard C. Schmidt  Gerd Rantitsch  Hilmar von Eynatten 《Geostandards and Geoanalytical Research》2014,38(1):73-94

Raman spectroscopy of carbonaceous material (RSCM) is frequently used to determine metamorphic peak temperatures from the structural order of carbonaceous material enclosed in metasediments. This method provides a quick, robust and relatively cheap geothermometer. However, the comparability of the RSCM parameter is low as there are at least three major sources of biasing factors. These sources are the spectral curve‐fitting procedure, the sample characteristics itself and the experimental design including the used Raman system. To assess the impacts of the biasing factors on RSCM, a series of experiments was performed. The experiments showed that curve‐fitting is strongly influenced by individual operator‐bias and the degrees of freedom in the model, implying the need for a standardised curve‐fitting procedure. Due to the diversity of components (optics, light detection device, gratings, etc.) and their combinations within the Raman systems, different Raman instruments generally give differing results. Consequently, to estimate comparable metamorphic temperatures from RSCM data, every Raman instrument needs its own calibration. This demands a reference material series that covers the entire temperature calibration range. Although sample heterogeneity will still induce some variation, a reference material series combined with standardised curve‐fitting procedures will significantly increase the overall comparability of RSCM data from different laboratories.  相似文献   

Optimization of novel hyperthermostable β amylase production by Bacillus subtilis DJ5 using solid agroresidual substrates     

A. Poddar  S. C. Jana 《International Journal of Environmental Science and Technology》2014,11(4):1127-1134

Eight different low cost starchy agroresidues namely Barley (B), Wheat bran (WB), Sattu (S), Rice powder (RP), Corn flour (CF), Rice husk (RH), Yellow peas split (YPS) and arrowroot (A) were used for solid culturing of Bacillus subtilis DJ5 for production of novel hyperthermostable β amylase. Various process parameters like initial moisture content, inoculum load, medium pH and incubation temperature affecting enzyme production were optimized to ensure maximum enzyme yield. Only 10 % inoculums load and medium pH of 6.9 was found sufficient to achieve maximum enzyme production in all substrates in a decreasing order, B > WB > S > RP > CF > RH > YPS > A. Optimum β amylase production was highly dependent on initial moisture content of substrate as observed from varying requirement of moisture for different substrates. Only 50 % moisture was sufficient for maximum enzyme production of 84.29 U/gdm in CF. For B, RH, YPS, and A 60 % initial moisture resulted in higher production of 120.34, 35.19, 26.59, and 21.58 U/gdm, respectively, at 37 °C. However, for S and RP higher (70 %) moisture content allowed 113.4 and 85.56 U/gdm enzyme production, respectively. Under optimized conditions, maximum β amylase production was observed after 25 h for A, YPS, RH, RP; 41 h for B, WB, CF, and 45 h for S.  相似文献   

Fe‐Mn systematics of type IIA chondrules in unequilibrated CO,CR, and ordinary chondrites     

Jana BERLIN  Rhian H. JONES  Adrian J. BREARLEY 《Meteoritics & planetary science》2011,46(4):513-533

Abstract– We have examined Fe/Mn systematics of 34 type IIA chondrules in eight highly unequilibrated CO, CR, and ordinary chondrites using new data from this study and prior studies from our laboratory. Olivine grains from type IIA chondrules in CO chondrites and unequilibrated ordinary chondrites (UOC) have significantly different Fe/Mn ratios, with mean molar Fe/Mn = 99 and 44, respectively. Olivine analyses from both these chondrite groups show well‐defined trends in Mn versus Fe (afu) and molar Fe/Mn versus Fe/Mg diagrams. In general, type IIA chondrules in CR chondrites have properties intermediate between those in UOC and CO chondrites. In most UOC and CR type IIA chondrules, the Fe/Mn ratio of olivine decreases during crystallization, whereas in CO chondrites the Fe/Mn ratio does not appear to change. It is difficult to interpret the observed Fe/Mn trends in terms of differing moderately volatile element depletions inherited from precursor materials. Instead, we suggest that significant differences in the abundances of silicates and sulfides ± metals in the precursor material, as well as open‐system behavior during chondrule formation, were responsible for establishing the different Fe/Mn trends. Using Fe‐Mn‐Mg systematics, we are able to identify relict grains in type IIA chondrules, which could be derived from previous generations of chondrules, including chondrules from other chondrite groups, and possibly chondritic reservoirs that have not been sampled previously.  相似文献   

The COVID-19 pandemic and global environmental change: Emerging research needs     

Robert Barouki  Manolis Kogevinas  Karine Audouze  Kristine Belesova  Ake Bergman  Linda Birnbaum  Sandra Boekhold  Sebastien Denys  Celine Desseille  Elina Drakvik  Howard Frumkin  Jeanne Garric  Delphine Destoumieux-Garzon  Andrew Haines  Anke Huss  Genon Jensen  Spyros Karakitsios  Jana Klanova  Iida-Maria Koskela  Francine Laden  Paolo Vineis 《Chemie der Erde / Geochemistry》2010

The outbreak of COVID-19 raised numerous questions on the interactions between the occurrence of new infections, the environment, climate and health. The European Union requested the H2020 HERA project which aims at setting priorities in research on environment, climate and health, to identify relevant research needs regarding Covid-19. The emergence and spread of SARS-CoV-2 appears to be related to urbanization, habitat destruction, live animal trade, intensive livestock farming and global travel. The contribution of climate and air pollution requires additional studies. Importantly, the severity of COVID-19 depends on the interactions between the viral infection, ageing and chronic diseases such as metabolic, respiratory and cardiovascular diseases and obesity which are themselves influenced by environmental stressors. The mechanisms of these interactions deserve additional scrutiny. Both the pandemic and the social response to the disease have elicited an array of behavioural and societal changes that may remain long after the pandemic and that may have long term health effects including on mental health. Recovery plans are currently being discussed or implemented and the environmental and health impacts of those plans are not clearly foreseen. Clearly, COVID-19 will have a long-lasting impact on the environmental health field and will open new research perspectives and policy needs.  相似文献   

Stable isotope profiles (Ca,O, C) through modern brachiopod shells of T. septentrionalis and G. vitreus: Implications for calcium isotope paleo-ocean chemistry     

Katja von Allmen  Thomas F. Nägler  Thomas Pettke  Dorothee Hippler  Erika Griesshaber  Alan Logan  Anton Eisenhauer  Elias Samankassou 《Chemical Geology》2010,269(3-4):210-219

Brachiopod shells are widely used as an archive to reconstruct elemental and isotopic composition of seawater. Studies, focused on oxygen and carbon isotopes over the last decades, are increasingly extending to the emerging calcium isotope system. To date, only little attention has been paid to test the reliability of fossil brachiopods on their modern counterparts.In this context, the present study investigates two modern brachiopods, Terebratulina septentrionalis (eastern Canada, 5–30 m depth, 7.1 °C seasonal temperature variation, two-layer shell) and Gryphus vitreus (northern Mediterranean, 200 m depth, constant all-year round temperature, three-layer shell). Both species were sampled along the ontogenetic growth direction and calcium, oxygen, and carbon isotopes as well as elemental concentration were measured. Calcium isotopes were analyzed on TIMS. The elemental composition was analyzed by LA-ICP-MS and ICP-AES.The results indicate an intra-specimen δ^44/40Ca variation ranging from 0.16 to 0.33‰, pointing to a fairly homogenous distribution of calcium isotopes in brachiopod shells. However, in the light of the suggested 0.7‰ increase in calcium isotopes over the Phanerozoic such intra-specimen variations constrain ocean reconstruction. δ^44/40Ca values of T. septentrionalis do not seem to be affected by growth rate. Calcium isotopic values of G. vitreus are heavy in the central part of the shell and trend towards lighter values in peripheral areas approaching the maximum isotopic composition of T. septentrionalis. The maximum inter-species δ^44/40Ca difference of 0.62‰ between T. septentrionalis and G. vitreus indicates that care should be taken when using different taxa, species with different strontium content or brachiopods with specialized shell structure, such as G. vitreus, for ocean water reconstruction in terms of Ca isotopic composition. T. septentrionalis may record Ca isotopic fractionation related to seasonal seawater temperature variations in its shell but this is difficult to resolve at the current analytical precision. Average δ¹⁸O-derived temperatures of the two investigated species are close to on-site measured temperatures.  相似文献   

Preparation and characterization of antibacterial silver/vermiculites and silver/montmorillonites   总被引：1，自引：0，他引：1  

Marta Valášková  Marianna Hundáková  Jana Seidlerová  Erich Pazdziora  Martin He?mánek  David Rafaja 《Geochimica et cosmochimica acta》2010,74(22):6287-6300

The reason for the preparation and characterization of the novel antibacterial silver/vermiculites (Ag/V) together with the silver/montmorillonites (Ag/M) was that the information on the vermiculite structure change and stability of Ag/V in water as well as its effect on bacteria are sporadic. The vermiculite (V), (Si_3.02Al_0.98)^IV (Mg_2.27Al_0.12Ti_0.07)^VI O₁₀(OH)₂ Ca_0.09Na_0.21K_0.50 from West China and montmorillonite (M), (Si_3.96Al_0.04)^IV (Al_1.20Mg_0.42Ti_0.02)^VI O₁₀ (OH)₂Ca_0.15Na_0.14K_0.08 from Ivan?ice (Czech Republic), fraction <0.4 μm were the starting clay materials for sample preparation. The samples V1 and M1 were prepared via reaction of the V and M with the 0.01 mol L⁻¹ AgNO₃ aqueous solution. The samples V2 and M2 were treated with the aqueous solution of AgNO₃ for two times. The cation exchange and reduced metallic silver on M1 and V1 evoked the specific surface area (SSA) diminution, the mean particle-size diameter extension and appearance of micropores with radius (<0.4 nm). Repeated silver cation exchange in M2 and V2 reduced particle size, increased slightly SSA and micropores with radius of 0.4-0.5 nm. Samples Ag/V and Ag/M showed higher content of pores with radius 0.5-1.0 nm than original V and M. The Ag concentration was found higher in Ag/V than in Ag/M and higher in repeatedly treated samples: 0.9 wt.% Ag in V1, 1.4 wt.% Ag in V2, 0.6 wt.% Ag in M1 and 1.0 wt.% Ag in M2. Vermiculite structure consisting of the hydrated interstratified phases and the mica-like phase changed to the cation-one-zero layer hydrate interstratification structure in V1 and to the random of two-one layer hydrate interstratifications in V2. Infrared and Mössbauer spectroscopy revealed no changes in the structure of the clay minerals that could be related directly to the sorption and crystallization of silver. Transmission electron microscopy showed that the silver nanoparticles size distribution was much narrower for the samples Ag/M than for Ag/V. The mean size of the Ag particles was between 40 and 50 nm. Although the Ag nanoparticles did not adhere sufficiently at the clay minerals surface and migrated moderately into water, all samples under study were approved to be effective inhibitors of the bacterial growth persisting for the whole testing period of 6 days. Silver/vermiculite was antimicrobial more efficient against Klebsiella pneumoniae and Pseudomonas aeruginosa than silver/montmorillonite.  相似文献   

The atmospheric impact on fluxes of nitrogen, POPs and energy in the German Bight     

M. Schulz  J. van Beusekom  K. Bigalke  U. Brockmann  W. Dannecker  H. Gerwig  H. Grassl  C. -J. Lenz  K. Michaelsen  U. Niemeier  T. Nitz  E. Plate  T. Pohlmann  T. Raabe  A. Rebers  V. Reinhardt  M. Schatzmann  K. H. Schlünzen  R. Schmidt-Nia  T. Stahlschmidt  G. Steinhoff  K. von Salzen 《Ocean Dynamics》1999,51(2-3):133-154

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